témavezető: Kollár László
helyszín (magyar oldal): PTE Faculty of Sciences, Institute of Chemistry helyszín rövidítés: TTK
A kutatási téma leírása:
Palladium-catalysed carbonylations such as alkoxy-, aryloxy- and aminocarbonylation reactions of N-heterocycles are planned. Iodo- and diiodo-triazols synthesised in ring-closure reactions will be used as substrates. Carbon monoxide and its surrogate, paraformaldehyde
are applied as carbonyl source. The application of environmentally benign solvents such as ionic liquids and biomass-based lactones will be studied. The possibility of single and double carbon monoxide insertion and the mechanistic issues of palladium-catalysed reactions are investigated.
1 PhD student (with good preparative skills) is expected.
előírt nyelvtudás: english felvehető hallgatók száma: 1