ODT - THESIS TOPIC: László Kollár: Homogeneous catalytic carbonylation of ...


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Thesis topic proposal

Homogeneous catalytic carbonylation of iodoalkenes and iodo(hetero)aromatics under environmentally benign conditions

THESIS TOPIC PROPOSAL

Institute: University of Pécs
chemistry
Doctoral School of Chemistry

Thesis supervisor: László Kollár
Location of studies (in Hungarian): University of Pécs, Faculty of Sciences, Institute of Chemistry
Abbreviation of location of studies: PTE

Description of the research topic:

Palladium-catalysed carbonylations such as alkoxy-, aryloxy- and aminocarbonylation reactions of iodoalkenes available from enolizable ketones, as well as iodoaromatics including N-heterocycles are planned. Among others, iodo- and diiodo-triazols, iodooxazoles and -thiazoles synthesised in ring-closure reactions will be used as substrates. Carbon monoxide and its surrogate, paraformaldehyde are applied as carbonyl source. The application of environmentally benign solvents such as ionic liquids and biomass-based lactones will be studied. The possibility of single and double carbon monoxide insertion and the mechanistic issues of palladium-catalysed reactions are also investigated.

Required language skills: english
Number of students who can be accepted: 2

Deadline for application: 2021-01-15

2024. IV. 17.
ODT ülés
Az ODT következő ülésére 2024. június 14-én, pénteken 10.00 órakor kerül sor a Semmelweis Egyetem Szenátusi termében (Bp. Üllői út 26. I. emelet).